Subscribe to RSS
Please copy the URL and add it into your RSS Feed Reader.
https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000084.xml
Synthesis 1999; 1999(1): 37-39
DOI: 10.1055/s-1999-3688
DOI: 10.1055/s-1999-3688
short paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved.
This journal, including all individual contributions and illustrations published therein,
is legally protected by copyright for the duration of the copyright period. Any use,
exploitation or commercialization outside the narrow limits set by copyright legislation,
without the publisher's consent, is illegal and liable to criminal prosecution. This
applies in particular to photostat reproduction, copying, cyclostyling, mimeographing
or duplication of any kind, translating, preparation of microfilms, and electronic
data processing and storage.cis-Hydroxylation of Cyclic Vinylsilanes Using Cetyltrimethylammonium Permanganate
Further Information
Publication History
Publication Date:
31 December 1999 (online)

Cetyltrimethylammonium permanganate (CTAP) effects cis-hydroxylation of cyclic vinylsilanes smoothly under mild conditions both in aqueous and nonaqueous solvents. cis-1-Trimethylsilylcycloalkane-1,2-diols 7-12 were prepared in good yields. The oxidation occurs at 20 °C and takes a much shorter time in comparison with OsO4 oxidation reported in the literature.
cis-hydroxylation - cyclic vinylsilanes - α,β-dihydroxysilanes - cetyltrimethylammonium permanganate - trimethylsilylcycloalkane-cis-diols